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Application of nanoscale zero valent iron (NZVI) for groundwater remediation in Europe

机译:纳米零价铁(NZVI)在欧洲地下水修复中的应用

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摘要

Nano Zero Valent Iron (NZVI) is emerging as new option for the treatment of contaminated soil and groundwater. Due to their small size, the nanoscale particles are more reactive than granular iron which is conventionally applied in reactive barriers and can be used for in situ treatment. NZVI effectively reduces chlorinated organic contaminants (e.g. TCE, PCE, TCA, pesticides, solvents) and also inorganic anions or metals. This article summarizes the current knowledge on NZVI for groundwater remediation and gives an overview over the practical experience on NZVI applications in Europe. The comparison of NZVI-applications in Europe and the U.S. reveals significant differences in the technology application. In Europe only three full-scale applications with surface-modified NZVI have been carried out so far while NZVI is an established treatment method in the U.S. Bimetallic particles and emulsified NZVI are currently not applied in Europe. The economic and legal conditions in Europe raise doubts that NZVI is a cost-effective method for groundwater remediation. Major concerns are the limited mobility and lifetime of NZVI. Further hurdles regarding the commercialization of NZVI are the material handling, the costs, the fear of a public backlash and that the technology is unknown to consultants, governments and site owners. However, the results of the field applications regarding contaminant reduction are promising and so far no major adverse impacts on the environment have been reported.
机译:纳米零价铁(NZVI)正在成为处理受污染的土壤和地下水的新选择。由于其尺寸小,纳米级颗粒比常规应用于反应性屏障的铁颗粒更具反应性,可用于原位处理。 NZVI有效地减少了氯化有机污染物(例如TCE,PCE,TCA,农药,溶剂)以及无机阴离子或金属。本文总结了有关NZVI用于地下水修复的最新知识,并概述了在欧洲使用NZVI的实践经验。在欧洲和美国对NZVI应用程序的比较表明,该技术应用程序存在显着差异。迄今为止,在欧洲,仅用表面改性的NZVI进行了三次大规模应用,而NZVI是美国公认的处理方法。目前在欧洲尚未使用双金属颗粒和乳化的NZVI。欧洲的经济和法律条件使人们怀疑NZVI是一种经济有效的地下水修复方法。主要问题是NZVI的机动性和使用寿命有限。有关NZVI商业化的其他障碍包括材料处理,成本,担心受到公众的抵制以及顾问,政府和站点所有者不知道该技术。然而,关于减少污染物的现场应用的结果是令人鼓舞的,迄今为止,尚未报道对环境的重大不利影响。

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